Apple don’t have any comprehensive pre-built GUI resources for app development, making it very hard to match the uniformed style of the iPhone or the iPad. You will need to create your own.
To help streamline your iPhone app design and development, we have put together a fairly comprehensive collection of iPhone & iPad GUI kits that will allow you to focus on developing rather than having to design everything from scratch.
Within this post you will find complete GUI kits and stencils, iPhone GUI elements and PSDs and finally a collection of the best icon-sets perfectly suited for the iPhone. (Some of the preview images are intentionally to large to show the as much of each GUI as possible).
Complete iPhone & iPad GUI Kits
iPhone PSD Vector Kit

This iPhone PSD Vector set, from Smashing Magazine and designed by Renee Rist, comes with several button elements as well as six different iPhone interface options.
iPhone PSD Vector Kit »
iPhone GUI PSD Design Template

iPhone GUI PSD Design Template »
iPhone Design Stencils – Yahoo Design Pattern Library

This iPhone Yahoo! Design Stencil Kit version 1.0 is available for OmniGraffle, Visio (XML), Adobe Illustrator (PDF and SVG), and Adobe Photoshop (PNG).
iPhone Design Stencils – Yahoo Design Pattern Library »
Ultimate iPhone Stencil (OmniGraffle)

This 'Ultimate Stencil' for OmniGraffle contains backgrounds, title bars, buttons, selectors, and almost all iPhone UI elements. The text is fully editable on lists, title bars, buttons, and scroll wheels and the buttons can be resized horizontally by ungrouping, resizing the middle element, and then regrouping the elements back into a single button.
Ultimate iPhone Stencil for OmniGraffle »
iPhone 3G Stencil (OmniGraffle)

This OmniGraffle stencil includes standard interface components for the iPhone 3G: buttons, fields, map elements, keyboards, icons… All of the components are on a transparent background and should re-size nicely.
iPhone 3G Stencil for OmniGraffle »
iPad and iPhone Design (OmniGraffle)

Design your application for iPhone, iPod touch and iPad devices with this exhaustive set of stencils. All stencils have been originally created by hand with native OmniGraffle shapes and groups and can be scaled, resized and exported to other vector formats in Graffle.
iPad and iPhone Design (OmniGraffle) »
FreshBooks iPhone Application GUI
FreshBooks iPhone Application GUI »
iPhone GUI as Rich Symbols for Fireworks

iPhone GUI as Rich Symbols for Fireworks »
iPhone UI Vector Elements
iPad GUI PSD Design Template
This PSD was constructed using vectors, so it’s fully editable and scalable. The workable screen design is formatted to 768×1024 so anything you design in the Photoshop file can easily be brought over to the SDK.
iPad GUI PSD Design Template »
iPad Vector GUI Elements

This GUI set contains almost all of the iPad UI elements, including buttons, tabs, menus, keyboard, ballons, etc… It also includes scalable and totally editable vector versions (AI).
iPad Vector GUI Elements »
iPhone GUI PSD Elements
MobileMe Full iPhone GUI
Matte iPhone UI
Sexy Vector Cell Phone
MobileMe Full GUI
iPhone 3G-3GS PSD
Apple iPad: Fully editable PSD
Apple iPad: Fully editable PSD »
Apple iPhone 4G .PSD
This. PSD is based on the controversial iPhone Gizmodo.com obtained and may not reflect the actual final product.
Apple iPhone 4G .PSD »
iPhone App Dev Icon Sets
iPhone Toolbar Icons

There are 160 clean and simple toolbar icons in this set designed specifically for the iPhone, with a source .psd file for futher customisation.
iPhone Toolbar Icons »
Glyphish’/>

The Glyphish icon set have designed and carefully optimized specifically for use on toolbars and tab bars in iPhone apps, but would also be perfect for Android Development.
The 130 icons are 24-bit .png images are about 30×30 pixels for tab bar icons and about 20×20 pixels for toolbar and navigation icons.
Glyphish »
iPhone Toolbar Icon Set

This set of 64 icons for the iPhone toolbar that contain beautiful shaded portions to give added depth and to highlight the icon features.
iPhone Toolbar Icon Set »
Free iPhone Toolbar Icons

These icons have been developed specifically for iPhone developers, completely free for anyone to use commercially under the Creative Commons Attribution 2.5 Canada license.
Free iPhone Toolbar Icons »
30 Free Vector Icons
iconSweets

iconSweets is a free icon set containing 60 vector Photoshop shapes, influenced by icon sets such as Glyphish and Pictoico. Perfectly suitable for iPhone & iPad app development.
iconSweets »
Touchscreen Hand Gestures v2 (OmniGraffle)

Vectorized version of Dan Saffer's "Touchscreen Hand Gestures" stencil (http://graffletopia.com/stencils/432) containing a collection of drawn hands for documenting touchscreen interactions.
Touchscreen Hand Gestures v2 (OmniGraffle) »
Gesturecons – Multi-Touch Icons

These vector based icons have been created to help in the design, development, implementation and promotion of multi-touch interfaces. You can use Gesturecons inside of your applications in order to demonstrate to users how to complete actions or prompt them to interact with an application when they approach it. You can scale them to any size and alter them in any way you wish.
Within the download package there are 52 high resolution vector icons entirely scalable and alterable (.pdf, .ai, .eps file types.).
Gesturecons – Multi-Touch Icons »
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30 Apr, 2010
Amazing collection for UI and concept designers. Love it.
30 Apr, 2010
Nice Collections…
30 Apr, 2010
Thanks a lot. It is really useful…
1 May, 2010
superb, ultimate nice and impressive collection :)
2 May, 2010
very nice collection indeed.
liked the hand gestures and iPad kits…
thanks a lot.
3 May, 2010
thx for the great stuff,i will work with is
7 May, 2010
Really nice round up. Thank you :)
16 Jun, 2010
iPad is way too cool to own, i wanna buy one next month.,*-
18 Jun, 2010
Amazing collection, helped me ALOT, keep up the good work!!!
10 Jul, 2010
Some really beautiful templates here..i love the GUI sets from teehanlax, for both iPhone and iPad..
There is another great guide on ipad app developmet on http://ipadappsplus.com/ipad-apps/how-to-create-ipad-apps/, that might be useful..
12 Aug, 2010
Excellent collection. I really like this. Thank you for sharing. Keep it up.
13 Aug, 2010
Great collection but I’m waiting for a Samsung Wave UI kit.
Iphone is not the only phone on the market and I’m sad about finding only apple’s related purposes :(
17 Aug, 2010
Thank you for this excellent selection. For making interactive prototypes for the iPad also check the iPad app called Picture Link. Demo video: http://www.zuhanden.de/apps/picturelink-app/
17 Aug, 2010
Awesome collection!! Its about 1000 man years’ designing effort in one post. :P
18 Aug, 2010
Thanks for sharing this excellent collections. its really useful.